Vis/NIR light driven mild and clean synthesis of disulfides in the presence of Cu2(OH)PO4 under aerobic conditions

Sk Sheriff Shah; S. Karthik; N. D.Pradeep Singh

doi:10.1039/c5ra05138j

Vis/NIR light driven mild and clean synthesis of disulfides in the presence of Cu₂(OH)PO₄ under aerobic conditions

Sk Sheriff Shah, S. Karthik, N. D.Pradeep Singh

Research output: Contribution to journal › Article › peer-review

23 Scopus citations

Abstract

A highly efficient one-pot strategy has been developed for the synthesis of disulfide in the presence of air under the irradiation of Vis/NIR light. Copper hydroxyphosphate (CHP) Cu₂(OH)PO₄, has been used as a Vis/NIR active photocatalyst. Disulfide forms on the surface of the catalyst by a radical mechanism. The protocol is useful for solvent free disulfide synthesis from a variety of thiols.

Original language	English (US)
Pages (from-to)	45416-45419
Number of pages	4
Journal	RSC Advances
Volume	5
Issue number	56
DOIs	https://doi.org/10.1039/c5ra05138j
State	Published - 2015
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

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10.1039/c5ra05138j

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abstract = "A highly efficient one-pot strategy has been developed for the synthesis of disulfide in the presence of air under the irradiation of Vis/NIR light. Copper hydroxyphosphate (CHP) Cu2(OH)PO4, has been used as a Vis/NIR active photocatalyst. Disulfide forms on the surface of the catalyst by a radical mechanism. The protocol is useful for solvent free disulfide synthesis from a variety of thiols.",

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N1 - Publisher Copyright: © The Royal Society of Chemistry 2015.

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Y1 - 2015

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AB - A highly efficient one-pot strategy has been developed for the synthesis of disulfide in the presence of air under the irradiation of Vis/NIR light. Copper hydroxyphosphate (CHP) Cu2(OH)PO4, has been used as a Vis/NIR active photocatalyst. Disulfide forms on the surface of the catalyst by a radical mechanism. The protocol is useful for solvent free disulfide synthesis from a variety of thiols.

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Vis/NIR light driven mild and clean synthesis of disulfides in the presence of Cu₂(OH)PO₄ under aerobic conditions

Abstract

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