X-ray photoelectron spectroscopy of S2N2 and the solid state polymerization of S2N2 to metallic (SN) x

J. Sharma; D. S. Downs; Z. Iqbal; F. J. Owens

doi:10.1063/1.435268

X-ray photoelectron spectroscopy of S₂N₂ and the solid state polymerization of S₂N₂ to metallic (SN) _x

J. Sharma
, D. S. Downs
, Z. Iqbal
, F. J. Owens

Research output: Contribution to journal › Article › peer-review

17 Scopus citations

Abstract

An x-ray photoelectron spectroscopic (XPS) study of a thin film of S ₂N₂ at -100°C, involving the valence band, core-level and core-level shakeup, and energy-loss spectra, is reported. The results are analyzed in terms of a molecular orbital model and previous optical data. In addition, the thermally induced solid state polymerization of S ₂N₂ to metallic (SN)_x was studied by recording the XPS spectra at -40, 0, and 20°C. The valence band data show changes of the highest filled molecular orbitale of S₂N₂, consistent with the process of polymerization to the metallic state.

Original language	English (US)
Pages (from-to)	3045-3049
Number of pages	5
Journal	The Journal of Chemical Physics
Volume	67
Issue number	7
DOIs	https://doi.org/10.1063/1.435268
State	Published - 1977
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1063/1.435268

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@article{971033d1f0814a9dac65764124f9828d,

title = "X-ray photoelectron spectroscopy of S2N2 and the solid state polymerization of S2N2 to metallic (SN) x",

abstract = "An x-ray photoelectron spectroscopic (XPS) study of a thin film of S 2N2 at -100°C, involving the valence band, core-level and core-level shakeup, and energy-loss spectra, is reported. The results are analyzed in terms of a molecular orbital model and previous optical data. In addition, the thermally induced solid state polymerization of S 2N2 to metallic (SN)x was studied by recording the XPS spectra at -40, 0, and 20°C. The valence band data show changes of the highest filled molecular orbitale of S2N2, consistent with the process of polymerization to the metallic state.",

author = "J. Sharma and Downs, \{D. S.\} and Z. Iqbal and Owens, \{F. J.\}",

year = "1977",

doi = "10.1063/1.435268",

language = "English (US)",

volume = "67",

pages = "3045--3049",

journal = "The Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "7",

}

TY - JOUR

T1 - X-ray photoelectron spectroscopy of S2N2 and the solid state polymerization of S2N2 to metallic (SN) x

AU - Sharma, J.

AU - Downs, D. S.

AU - Iqbal, Z.

AU - Owens, F. J.

PY - 1977

Y1 - 1977

N2 - An x-ray photoelectron spectroscopic (XPS) study of a thin film of S 2N2 at -100°C, involving the valence band, core-level and core-level shakeup, and energy-loss spectra, is reported. The results are analyzed in terms of a molecular orbital model and previous optical data. In addition, the thermally induced solid state polymerization of S 2N2 to metallic (SN)x was studied by recording the XPS spectra at -40, 0, and 20°C. The valence band data show changes of the highest filled molecular orbitale of S2N2, consistent with the process of polymerization to the metallic state.

AB - An x-ray photoelectron spectroscopic (XPS) study of a thin film of S 2N2 at -100°C, involving the valence band, core-level and core-level shakeup, and energy-loss spectra, is reported. The results are analyzed in terms of a molecular orbital model and previous optical data. In addition, the thermally induced solid state polymerization of S 2N2 to metallic (SN)x was studied by recording the XPS spectra at -40, 0, and 20°C. The valence band data show changes of the highest filled molecular orbitale of S2N2, consistent with the process of polymerization to the metallic state.

UR - https://www.scopus.com/pages/publications/3042893147

UR - https://www.scopus.com/pages/publications/3042893147#tab=citedBy

U2 - 10.1063/1.435268

DO - 10.1063/1.435268

M3 - Article

AN - SCOPUS:3042893147

SN - 0021-9606

VL - 67

SP - 3045

EP - 3049

JO - The Journal of Chemical Physics

JF - The Journal of Chemical Physics

IS - 7

ER -

X-ray photoelectron spectroscopy of S₂N₂ and the solid state polymerization of S₂N₂ to metallic (SN) _x

Abstract

All Science Journal Classification (ASJC) codes

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